【摘 要】
：
A novel ionic compound [Fe(CN)6·(PhCH2N C9H7)4]·12H2O (C70H80FeN10O12,Mr =1309.29) has been synthesized and its structure was characterized by IR,elemental an
【机 构】
：
College of Chemistry Chemical Engineering
论文部分内容阅读
A novel ionic compound [Fe(CN)6·(PhCH2N C9H7)4]·12H2O (C70H80FeN10O12,Mr =1309.29) has been synthesized and its structure was characterized by IR,elemental analysis and X-ray diffraction.The compound crystallizes in triclinic,space group P(1),with a=10.968(7),b=11.466(7),c=14.077(8) (A),a=87.014(7),β=78.124(7),y=72.708(7)°,V=1654.1(17) (A)3,Z=1,Dc=1.314 g·cm-3,F(000)=692,μ=0.298 mm-1,the final R=0.0519 and wR=0.1355.The building unit of the title compound consists of four (PhCH2N+C9H7) ions,one [Fe(CN)6]4- anion,and a dozen water molecules.According to the structural analysis,[Fe(CN)6]4- ions are linked together by O-H…O and O-H…N hydrogen bonds,while (PhCH2N+C9H7) and [Fe(CN)6]4- ions interact with each other by electrostatic force to form an ionic compound.
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