1859年,Hallwachs在試驗室中製得了有機鋁化合物,一直到1924年Grignard才分離和鑑定出這些化合物。后來Grosse等進行了一系列的有機鋁化合物的製備研究,至今仍是最詳盡的文獻之一。但總的看來,在有機金屬化合物中,有機鋁化合物過去是研究得很少的一個,也沒有什麼應用。 In 1859, Hallwachs produced organoaluminum compounds in the laboratory, which were not isolated and identified until 1924 by Grignard. Later, Grosse et al. Conducted a series of studies on the preparation of organoaluminum compounds, which is still one of the most detailed documents to date. In general, however, organoaluminum compounds have historically been the less studied and of no use in organometallic compounds.