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［Ｚｎ（Ｉｍ）２］ｎ晶体属四方晶系，空间群Ｉ４１ｃｄ，晶胞参数ａ＝２３５７．２（３）ｐｍ，ｂ＝２３５７．２（３）ｐｍ，ｃ＝１２４６．７（２）ｐｍ，Ｖ＝６．９２７（２）×１０９ｐｍ３，Ｚ＝３２．配合物晶体不对称结构单元中有２个独立Ｚｎ（Ⅱ）原子，它们处于非常相似的配位环境．每个Ｚｎ（Ⅱ）原子与４个脱氢的咪唑氮原子配位形成四面体配位结构．每个脱氢的咪唑配体起到μ２桥的作用，连接１对相邻的Ｚｎ（Ⅱ）原子，其中，Ｚｎ…Ｚｎ间距为５９１．８（１）～６０２．９（１）ｐｍ．固态时，Ｚｎ（Ⅱ）原子与μ２－咪唑桥交替相连成为三维网状结构，并形成沿ｃ轴延伸的洞状结构．
The crystal of [Zn (Im) 2] n belongs to the tetragonal system with space group I41cd. The unit cell parameters are a = 2357.2 (3) pm, b = 2357.2 , V = 6.927 (2) × 109 pm3, Z = 32. There are two independent Zn (II) atoms in the asymmetric structure unit of the complex crystal, which are in a very similar coordination environment. Each Zn (Ⅱ) atom coordinates with four dehydrogenated imidazole nitrogen atoms to form a tetrahedral coordination structure. Each dehydrogenated imidazole ligand acts as a [mu] 2 bridge connecting one pair of adjacent Zn (II) atoms, with Zn ... Zn spacing of 591.8 (1) to 602.9 (1) pm. Solid state, Zn (Ⅱ) atoms and μ2-imidazole bridge alternately connected into a three-dimensional network structure, and the formation along the c-axis extending hole structure.