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本文合成了四（对－氯代甲基）苯基－甲基紫精卟啉及其Ｚｎ、Ｃｏ、Ｍｎ配合物，用元素分析、红外光谱和紫外可见光谱进行了表征．研究了它们的光化学性质．结果表明．在ＴＥＯＡ中光照使Ｍ·ＴＣＭＰＰ—ｍｖ￣２＋发生了分子内从卟啉到甲基紫精的电子迁移反应．在ＺｎＴＣＭＰＰ－ｍｖ￣２＋／ＴＥＯＡ／ＤＭＳＯ—Ｈ２Ｏ体系中可发生光敏化还原ｍｖ２＋反应，生成较稳定的ｍｖ＋．在Ｍｎ（Ⅲ）ＴＣＭＰＰ－ｍｖ２＋／ＣＨ３ＯＨ／Ｈ２Ｏ体系中可发生光助氧化甲醇反应，并检出了氧化产物甲醛．
In this paper, tetrakis (p-chloromethyl) phenyl-methyl viologen porphyrin and its complexes of Zn, Co and Mn were synthesized and characterized by elemental analysis, IR and UV-Vis spectra. Their photochemical properties were studied. The results show. The photolysis in TEOA caused the intramolecular electron transfer reaction of MTPMPP-mv2 + from porphyrin to methyl viologen. Photochemical reduction of mv2 + can occur in ZnTCMPP-mv ~ 2 + / TEOA / DMSO-H2O system, resulting in a more stable mv +. In the Mn (Ⅲ) TCMPP-mv2 + / CH3OH / H2O system, the photooxidation of methanol can occur and the formaldehyde of the oxidation product is detected.