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研究了组成为ＲＥ（Ｈｉｓ）（ＮＯ３ ）３ ·Ｈ２Ｏ（ＲＥ＝ Ｌａ～Ｎｄ，Ｓｍ ～Ｌｕ，Ｙ；Ｈｉｓ＝ Ｌ－α－ｈｉｓｔｉｄｉｎｅ）固态配合物的拉曼光谱。结果表明，配合物中ＲＥ３＋ 与羧基氧原子配位，氨基和味唑环均未参与配位，ＮＯ－３ 为双齿配位。配合物羧基振动峰的Δνａｓ－ｓＣＯＯ－ 与镧系离子的原子序数作图服从Ｏｄｄｏ－Ｈａｒｋｉｎｓ规律
The Raman spectra of solid-state complexes with RE (His) (NO3) 3 · H2O (RE = La ~ Nd, Sm ~ Lu, Y; His = L-α-histidine) were studied. The results showed that the coordination between RE3 + and carboxyl oxygen atom in the complex did not take place in the amino group and the imidazole ring, and NO-3 was bidentate. Complexes carboxyl vibration peak Δνas-sCOO- and lanthanide ion atomic number plot obeys the Oddo-Harkins law