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研究了碘化四－（４－三甲胺基苯基）卟啉钴和ＶＢ_（１２）催化ＣＯ_２与卤代丁烷的电合成。该反应在－１．５Ｖ（ｖｓ．ＳＣＥ）即可发生，ＶＢ_（１２）催化产物为预期的戊酸丁酯，而ＣｏＴＰＰ催化产物为ＣＯ_２直接还原的草酸二丁酯，并未发现ＣＯ_２与卤代丁烷的反应产物。初步探讨了产生不同产物的原因．
The electrochemical synthesis of CO_2 and halogenated butane catalyzed by tetrakis (4-trimethylaminophenyl) porphyrin iodide and VB_ (12) was studied. The reaction takes place at -1.5 V (vs.SCE), the expected VB_ (12) product is the expected butyl valerate, and the COTPD catalyst is the dibutyl oxalate which is directly reduced by CO_2. Butane reaction product. Preliminary discussion of the reasons for the different products.