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The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystallographic data are as follows: monoclinic, space group P21, a=0.63464(13)nm, b=1.9110(4)nm, c=0.87367(17)nm, β=97.67(3)°, Z=2, V=1.0501(4)nm3, Dc=1.571g·cm-3, μ=1.546mm-1, F(000)=500, R=0.0209, wR=0.0381 [I ≥2σ(I)]. The str uctures consist of discrete molecules containing five coordinate tin atoms in a seriously distorted trigonal bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.
The chlorodibenzyltin dithiopiperidylcarbamate was synthesized by the reaction of dibenzyltin dichloride with dithiopiperidylcarbamate and was characterized by elemental analysis, IR and 1H NMR. The crystal structure was determined by X ray single crystal diffraction. The crystalographic data was as follows: monoclinic, space group P21, a = 0.63464 (13) nm, b = 1.9110 (4) nm, c = 0.87367 (17) nm, β = 97.67 (3) °, Z = 2, V = 1.0501 (4) nm3 and Dc = 1.571 g · cm -3, μ = 1.546 mm-1, F (000) = 500, R = 0.0209, wR = 0.0381 [I ≧ 2σ (I)]. The str uctuations consist of discrete molecules containing five coordinate tin atoms in a serious distorted trigonal Bipyramidal configuration. The molecules are packed in the unit cell in one dimensional chain complex through a weak interaction between the chlorine atom, the sulfur atom and one of the other sulfurs of an adjacent molecule. CCDC: 180034.