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由于高分子具有尺寸长短不一、柔性等特点,很难通过普通方法合成具有结晶性和多孔性的高分子材料。而高分子金属配合物材料不仅继承了高分子材料的传统性质,同时也可以获得配合物的优点,比如高结晶性和多孔性。本文系统总结了合成结晶性的多孔高分子配合物材料的方法,包括光诱导聚合法、配位自主装法、分步合成法以及后修饰法。同时介绍了它们的表征方法以及潜在应用领域,并讨论了该领域研究中存在的各种机遇与挑战。
Due to the different sizes and flexibility of polymers, it is difficult to synthesize macromolecular materials with crystallinity and porosity by ordinary methods. The macromolecule metal complex material not only inherits the traditional nature of polymer materials, but also can obtain the advantages of the complex, such as high crystallinity and porosity. This paper systematically summarizes the method of synthesis of crystalline porous polymer complex materials, including light-induced polymerization method, the coordination of self-installed method, step by step synthesis and post-modification method. At the same time, the methods of their characterization and their potential applications are introduced. The opportunities and challenges in the research of this field are also discussed.