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在乙腈酸性水溶液中 ,考察了 Fe Pc(酞菁铁 )和 Fe-Poly Pc(聚酞菁铁 )的制备方法对 Pd( OAc) 2 /HQ(氢醌 ) /MLn( Fe Pc,Fe-Poly Pc)催化环己烯氧化活性的影响。通过元素分析、UV-Vis、IR对酞菁铁的结构进行了初步分析 ,结果表明 ,Pd( OAc) 2 /HQ(氢醌 ) /Fe Pc的催化活性与 Fe Pc中的 μ-氧酞菁铁含量有关。聚酞菁铁在该催化体系中的活性较低
The preparation method of FePC (iron phthalocyanine) and Fe-PolyPC (iron phthalocyanine) was investigated in acetonitrile aqueous solution. The effects of Pd (OAc) 2 / HQ Pc) to catalyze the oxidation of cyclohexene. The structure of iron phthalocyanine was analyzed by elemental analysis, UV-Vis and IR. The results showed that the catalytic activity of Pd (OAc) 2 / HQ (hydroquinone) / Fe Pc was similar to that of μ-oxyphthalocyanine Iron content. Polyphthalocyanine iron is less active in this catalytic system