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柯尔蜀夫曾发现在1摩尔浓度碘化钾溶液中有一显著的且不易抑制的极谱波。此后,kalvoda研究出镉离子在六次甲基四胺和硫氰酸铵存在下有一催化吸附波。陈德真试验了在六次甲基四铵溶液中加入碘离子所形成的镉碘络离子的催化吸附
Kohlhoff has found a significant and non-suppressed polarographic wave in a 1 molar potassium iodide solution. Since then, kalvoda has developed a cadmium ion in the presence of hexamethylenetetramine and ammonium thiocyanate in the presence of a catalytic adsorption wave. Chen Dezhen tested the hexamethylenetetramine solution by adding iodine ion formed by the cadmium iodide ion catalytic adsorption