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四甲基苯醌在氯化正丁基吡啶－ＡｌＣｌ＿３室温熔盐中的电化学行为，和室温熔盐的酸碱度有关，在碱性熔盐中，四甲基苯醌以不络合的形式存在，电极上的还原过程是一个ＥＣＥ过程；在酸性熔盐中，形成络合物ＴＱ（ＡｌＣｌ＿３）＿ｍ，络合数ｍ为１，２，３，随熔盐酸度变化，此外，醌类物质芳香环上的取代基，也影响其电化学性质。吸电子基团使还原电位正移，推电子基团使还原电位负移。
The electrochemical behavior of tetramethylbenzoquinone in room temperature molten salt of n-butylpyridine-AlCl_3 is related to the pH value of molten salt at room temperature. In alkaline molten salt, tetramethylbenzoquinone exists in non-complex form , The reduction process on the electrode is an ECE process; in the acidic molten salt, the complex TQ (AlCl 3) _m is formed, the complex number m is 1, 2 and 3, with the change of the acidity of the molten salt, The substituents on the ring also affect their electrochemical properties. Electron-withdrawing groups move the reduction potential forward, pushing the electron groups to negatively shift the reduction potential.