A new self-assembled monolayer (SAM) of fulerene derivative has been fabricated and their photoelectric conversion property has been observed. The SAM was fabricated on indium-tinoxide (ITO) and quartz by amide bonding. It was characterized by contact angle. UV spectrum. andcyclic voltammetry. The mild fabrication conditions and the stability of the SAM provides a way tobuild three-dimensional structure more easily.