Many biological surface are hydrophobic because of their complicated composition and surface microstructure. Eleven species (four families) of butterflies were selected to study their micro-, nano-structure and super-hydrophobic characteristic by means of Confocal Light Microscopy, Scanning Electron Microscopy and Contact Angle Measurement. The contact angles of water droplets on the butterfly wing surface were consistently measured to be about 150° and 100° with and without the squamas, respectively. The dust on the surface can be easily cleaned by moving spherical droplets when the inclining angle is larger than 3°. It can be concluded that the butterfly wing surface possess a super-hydrophobic, water-repellent,self-cleaning, or "Lotus-effect" characteristic. The contact angle measurement of water droplets on the wing surface with and without the squamas showed that the water-repellent characteristic is a consequence of the microstructure of the squamas.Each water droplet (diameter 2 mm) can cover about 700 squamas with a size of 40 μm×80 μm of each squama. The regular riblets with a width of 1000 nm to 1500 nm are clearly observed on each single squama. Such nanostructure should play a very important role in their super-hydrophobic and self-cleaning characteristic.