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研究了新试剂4-(H酸偶氮)-1-苯基-3-甲基吡唑啉酮(HAPMP)与铁的显色反应,在pH7的NH4Ac缓冲介质中,CTMAB存在下,HAPMP与Fe(Ⅲ)生成3:1的紫色络合物.λmax=610nm,ε=7.68×104,铁含量在0~10μg/25mL内符合比尔定律,方法用于水样和镁合金中铁的测定.结果满意.
The color reaction of the new reagent 4- (H-azo) -1-phenyl-3-methylpyrazolone (HAPMP) with iron was studied. In the NH4Ac buffer medium of pH7, Fe (III) generates a 3: 1 purple complex. λmax = 610nm, ε = 7.68 × 104, Beer’s law is obeyed in the range of 0 ~ 10μg / 25mL. The method is applied to the determination of iron in water sample and magnesium alloy. Satisfactory results.