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A new electrochemical oscillatory system of bromate in alkaline solution is reported.In Pt-Bromate-Alkaline solution system,two different types of electrochemical oscillations(Type Ⅰ and Type Ⅱ) can be observed.Type Ⅰ appears before hydrogen evolution and Type Ⅱ involves periodic hydrogen evolution.Type Ⅰ relates to the adsorption/desorption of the hydrogen on platinum electrode,and Type Ⅱ with periodic oscillation stems from the coupling of electrochemical reactions(the reduction of bromate and evolution hydrogen reaction) with mass transfer(diffusion and convection).More over,under the right conditions,the two types appear in different oscillatory modes,for example,simple periodical mode and mixed one,etc..Crossed cycle in the cyclic voltammograms,which is the basic characteristics for electrochemical oscillatory systems,has also been observed as expected.
A new electrochemical oscillatory system of bromate in alkaline solution is reported. Pt-Bromate-Alkaline solution system, two different types of electrochemical oscillations (Type I and Type II) can be observed. hydrogen evolution. Type I related to the hydrogen on platinum electrode, and Type II with periodic oscillation stems from the coupling of electrochemical reactions (the reduction of bromate and evolution hydrogen reaction) with mass transfer (diffusion and convection). More over, under the right conditions, the two types appear in different oscillatory modes, for example, simple periodical mode and mixed one, etc .. Crossed cycle in the cyclic voltammograms, which is the basic characteristics for electrochemical oscillatory systems, has also been viewed as expected.