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1906年卡佛利尔(Cavalier),报导了用焦磷酸銀和碘代丁烷制备焦磷酸四丁酯(TBPP).此后,伍德斯托克(Woodstock),托伊(Toy)和密恰尔斯基(Michalski)等人陆續提出了不同的合成方法。1962年陆熙炎等人以正丁醇和三氯化磷为原料,用二正丁基磷酰氯控制水解的方法制备了TBPP。标記P~(32)-TBPP的合成至今尚未見到报导。1948年托伊报导了TBPP的物理常数和水解性貭,1958年肯尼迪(Kennedy)报导了TBPP对硝酸鈾酰的萃取性能。但至今对TBPP性貭的研究尚不多,TBPP是否有前途作为一种核燃料萃取剂的問題也尚未解决。为此,我們合成了标記P~(32)-TBPP,并进一步研究了它的水解性貭和輻照稳定性。
Cavalier 1906 reported the use of silver pyrophosphate and iodobutane for the preparation of tetrabutyl pyrophosphate (TBPP). After that, Woodstock, Toy and Mycenaar Michalski and others have proposed different synthesis methods one after another. In 1962, Lu Xiyan et al. Used n-butanol and phosphorus trichloride as raw materials to prepare TBPP by controlling the hydrolysis with di-n-butylphosphoryl chloride. The synthesis of the marker P ~ (32) -TBPP has not been reported yet. 1948 Toi reported on the physical constants and hydrolytic properties of TBPP, and in 1958 Kennedy reported TBPP extraction performance of uranyl nitrate. However, up to now, few studies on TBPP have been conducted, and the question of whether TBPP has any future as a fuel extractant has not yet been solved. To this end, we synthesized the labeled P ~ (32) -TBPP and further studied its hydrolytic stability and radiation stability.