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针对四川攀西 w( MnO) = 8-2 % 的稀土矿泥,采用SO2 作还原剂,在200 L 反应釜中进行预脱锰,在n(SO2) n( Mn) = 2-4 ,LS= 3∶1 的条件下,锰的浸出率为70 % 以上,而稀土及铁的浸出率分别小于1 % 及3 % 。锰浸出液除杂后采用碳酸氢铵沉淀得到碳酸锰产品, 产品纯度达到96-78 % 。脱锰矿泥与氯化铵按m(NH4 Cl) m( 矿泥) = 0-2 ~0-3 混合,在520 ℃下焙烧2-5 h ,稀土浸出率达到80 % 以上,比原矿泥直接氯化焙烧的回收率提高约40 % 。
According to the rare earth slime with 8 ~ 2% Mn in Panxi, Sichuan Province, pre-demineralization was carried out in 200 L reactor using SO2 as reductant, Under the conditions of LS = 3:1, the leaching rate of manganese is over 70%, while the leaching rates of rare earth and iron are less than 1% and 3% respectively. Manganese leaching solution after impurity removal using ammonium bicarbonate precipitation manganese carbonate products, the product purity of 96-78%. Manganese-mined slime and ammonium chloride are mixed according to m (NH4Cl) m (slime) = 0-2 ~ 0-3, calcined at 520 ℃ for 2-5 h, and the leaching rate of rare earth reaches more than 80% Direct chlorination roasting recovery rate increased by about 40%.