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Reaction of WCl6, mpH2 o-mercaptophenol) and MeONa in the presence of Ph4PBr gave complexes (Ph4P)[W(mp)3] (1) and (Ph4P) CWO(OMe) (mp)2] (2). Crystal data complex (2), C37H31O4PS2W, Mr = 818. 61, monoclinic, space group P2/a, a=26. 555(3), b=9. 634(1), c=13. 523(7) A. β=94. 68 (2)°, V=3448. 1 A3. A=1. 58 g/cm3, Z = 4. λ(MoKα)=0. 71073 A , μ= 36. 2 cm-1, F(000) = 1624, T=296K, final R(Rw) = 0. 068(0. 070) for 3929 observed reflections. The WO4S2 core is arranged in a distorted octahedral geometry.
Reaction of WCl6, mpH2 o-mercaptophenol) and MeONa in the presence of Ph4PBr gave complexes (Ph4P) [W (mp) 3] (1) and (Ph4P) CWO (OMe) (mp) 2] complex (2), C37H31O4PS2W, Mr = 818. 61, monoclinic, space group P2 / a, a = 26.555 (3), b = 9.634 (1), c = = 94.68 (2) °, V = 3448.1 A3. A = 1.58 g / cm3, Z = 4. λ (MoKα) = 0. 71073 A, μ = 36.2 cm -1, F 000) = 1624, T = 296K, final R (Rw) = 0.068 (0.070) for 3929 observed reflections. The WO4S2 core is arranged in a distorted octahedral geometry.