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Catalytic properties of the metal-organic framework Cr-MIL-101 in solvent-free cycloaddition of CO2to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25C). Styrene and propylene carbonates were formed with high yields (95% and 82%, respectively). Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW 12 /Cr-MIL-101 composite material have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H2O2 as oxidants at 8 100 bar CO2and 25 80C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.
Catalytic properties of the metal-organic framework Cr-MIL-101 in a solvent-free cycloaddition of CO2to epoxides to produce cyclic carbonates using tetrabutylammonium bromide as co-catalyst have been explored under mild reaction conditions (8 bar CO2, 25C) Catalytic performance of Cr-MIL-101 was compared with other MOFs: Fe-MIL-101, Zn-MOF-5 and HKUST-1. The catalytic properties of different quaternary ammonium bromides, Cr-MIL-101 as well as PW 12 / Cr-MIL-101 composite materials have been assessed in oxidative carboxylation of styrene in the presence of both tert-butyl hydroperoxide and H2O2 as oxidants at 8 100 bar CO2and 25 80C with selectivity to styrene carbonate up to 44% at 57% substrate conversion.