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合成了苄基环戊二烯基二氯化钕配合物(C6H5CH2C5H4NdCl2·3THF).用元素分析、红外光谱分析对其结构进行了表征,该配合物与三乙基铝(AlEt3)组成的催化体系催化丁二烯聚合,单体转化率达85%.
Synthesis of a benzylcyclopentadienyl neodymium dichloride complex (C6H5CH2C5H4NdCl2 · 3THF). The structure was characterized by elemental analysis and infrared spectroscopy. The catalytic system composed of the complex and AlEt3 Catalysis butadiene polymerization, monomer conversion rate of 85%.