【摘 要】
：
The title complex, [Zn(ip)_2(H_2O)_2][ZnCl_4].H_2O.2DMF 1 (ip = imidazo[4,5-f][1,10]phenanthroline), has been synthesized via the slow evaporation of concentrat
【机 构】
：
State Key Laboratory of Structural Chemistry,Graduate
【基金项目】
：
NSF of Fujhn Province;国家自然科学基金;The project was supported by 973 Program
论文部分内容阅读
The title complex, [Zn(ip)_2(H_2O)_2][ZnCl_4].H_2O.2DMF 1 (ip = imidazo[4,5-f][1,10]phenanthroline), has been synthesized via the slow evaporation of concentrated reaction solution at room temperature. It was characterized by single-crystal X-ray diffraction. Crystal data for C_(32)H_(36)Cl_4N_(10)O_5Zn_2: white prism, 0.17mm × 0.15mm × 0.10mm, monoclinic, space group P2/c, a =11.928(8), b = 9.868(6), c = 16.520(11) (A), β= 104.879(12)°, V= 1879(2) (A)~3, Z= 2, M_r = 913.25, D_c= 1.614 g/cm~3,/7(000) = 932,μ = 1.616 mm~(-1), λ(MoKα) = 0.71073 (A), GOOF = 1.045, R = 0.0710and wR = 0.1755 for 3055 observed reflections with I > 2σ(/). X-ray diffraction study reveals that the title eomplex has an interesting 3D architecture via hydrogen bonding interactions and π-πinteractions. The IR, TGA, XRD and luminescent properties of complex 1 were also studied.
其他文献
A model is presented for the simulation of reactive gas-solids flows in large industrial reactors. Circulating fluidized bed (CFB) combustors with several thous
Self-positioning of a shearer is the key technology for mining with a man-less working face. In an underground coal mine all radio navigation; satellite positio
Using GIS, GPS and GPRS, a dynamic management system of ore blending in an open pit mine has been designed and developed. A linear program was established in a
A relatively high predetermined crystallization temperature(135℃)was chosen to grow well developed iPP spherulites,then the partial melting was carried out at
The general computational approach of Stochastic Gradient Boosting (SGB) is seen as one of the most powerful methods in predictive data mining. Its applications
Three compounds modeled on the lignite structure were chosen for experimental degradation by different fungi strains. Culture conditions and extracellular enzym
In this study, combustion of methane was simulated using four kinetic models of methane in CHEMKIN 4.1.1 for 0-D closed internal combustion (IC) engine reactor.
A series of novel 7-(4-alkoxyimino-3-hydroxypiperidin-l-yl)quinolone derivatives were designed, synthesized and evaluated for in vitro antibacterial activities.
The title complex[Cp~*Ir{N(Ph_2PS)_2}(N_3)](N(Ph_2PS)_2=bis(diphenylthiophosphoryl)amide,Cp~*=pentamethylcyclopentadienyl)has been prepared and characterized by
Comparison in electron transfer (ET) processes from decamethyferrocene (DMFe) in nitrobenzene (NB) to ferric ion in aqueous phase was investigated for the first