直链淀粉手性固定相对8种外消旋硫代缩水甘油醚的直接拆分

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利用高效液相色谱进行不对称拆分是十分有效的方法,其中多糖类手性固定相是非常重要的一种,它主要包括纤维素和淀粉两大类,Okamoto等[1~3]合成了大量的纤维素和直链淀粉的衍生物,并将其涂敷在大孔硅胶表面,从而制备了手性拆分能力较强的多种固定相,这类... Asymmetric resolution using high performance liquid chromatography is a very effective method, of which polysaccharide chiral stationary phase is a very important one, which includes two major categories of cellulose and starch, Okamoto et al [1 ~ 3] Synthesis A large number of derivatives of cellulose and amylose are coated on the surface of a macroporous silica gel to prepare a variety of stationary phases with strong chiral resolution capability.
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