One-step Crystallization Kinetic Parameters of the Glass-ceramics Prepared from Stainless Steel Slag

来源 :Journal of Iron and Steel Research(International) | 被引量 : 0次 | 上传用户:hfzwl
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One-step crystallization is one of the most energy conserving methods for glass-ceramics preparation.However,only a few kinetics studies focused on the glass-ceramics prepared by the one-step crystallization.The onestep crystallization kinetic parameters were studied using differential scanning calorimetry.The activation energy(Ea)and the Avrami parameter(n)were calculated as 152.79kJ·mol-1 and 4.39,respectively.These parameters indicate that continuous nucleation and three-dimensional crystal growth are the dominating mechanisms in the one-step crystallization process of the parent glass.The properties of the obtained glass-ceramics can be compared to the glass-ceramics prepared by the two-stage heat treatment and sintering method.This crystallization kinetics research can be used to evaluate the one-step crystallization potential of a parent glass. One-step crystallization is one of the most energy conserving methods for glass-ceramics preparation. Despite, only a few kinetics studies studies on the glass-ceramics prepared by the one-step crystallization. The onestep crystallization kinetic parameters were studied using differential scanning calorimetry . The activation energy (Ea) and the Avrami parameter (n) were calculated as 152.79 kJ · mol-1 and 4.39, respectively. These parameters of that nucleation and three-dimensional crystal growth are the dominating mechanisms in the one-step crystallization process of the parent glass.The properties of the obtained glass-ceramics can be compared to the glass-ceramics prepared by the two-stage heat treatment and sintering method.This crystallization kinetics research can be used to evaluate the one-step crystallization potential of a parent glass.
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