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(Et_4N)_2[Fe_2S_2(SC_6H_4Cl-p)_4], Mr=939.89, F(000)=492, triclinic, P1,a=9.358(4), b=10.535(3), c=14.537(2)A,α=64.96(2),β=70.29(2),γ= 68.22(2)°, V=1177.8(13)A3, Z=1,Dc=1.325 gcm-3, MoKα ,λ=0.71069A. Final R= 0.061,Rw=0.076, for 1794 independent observed reflections. The anion contains a planar Fe2S2 core. Each iron atom is coordinated by two μ2-S atoms and two thiolate sulfur atoms to form the tetrahedral geometry. The structure of the cation has its positional disorder.
(Et_4N) _2 [Fe_2S_2 (SC_6H_4Cl-p) _4], Mr = 939.89, F (000) = 492, triclinic, P1, a = 9.358 (4), b = 10.535 (3), c = 14.537 , α = 64.96 (2), β = 70.29 (2), γ = 68.22 (2) °, V = 1177.8 (13) A3, Z = 1, Dc = 1.325 gcm-3, MoKα, λ = 0.71069A. Final The iron atoms are coordinated by two μ2-S atoms and two thiolate sulfur atoms to form the tetrahedral geometry. The structure of the cation has (R = 0.061, Rw = 0.076, for 1794 independent observed reflections. its positional disorder.