前文根据零电荷电位的概念和水的結构理論,初步地解释了阴离子对极化的影响。本文研究温度和阴离子对鎘电沉积速度的影响,根据試驗数据,討論鎘电沉积的极化性质,井由計算所得的活化能值进一步闡明阴离子在电积过程中的作用,提出阴离子效应的概念。文献中有关阴离子对金属电沉积影响的实驗均在18～25℃同进行。在不同温度下研究阴离子影响的工作还很少见。和在25～75℃ According to the concept of zero charge potential and the theory of water structure, we have preliminarily explained the effect of anions on polarization. In this paper, the effects of temperature and anions on the deposition rate of cadmium were investigated. According to the experimental data, the polarization properties of cadmium electrodeposition were discussed. The calculated activation energy values ​​further elucidated the role of anions in the electrodeposition process and proposed the concept of anion effect . The literature on the impact of anions on the metal electrodeposition experiments were carried out at 18 ~ 25 ℃. It is rare to study the effect of anions at different temperatures. And at 25-75 ° C