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阐述了受限制的复杂反应体系不同于一般反应平衡体系的特点,并介绍了添入附加的物质守恒限制条件,用自由能最小化方法来计算受限制的复杂反应体系组成.编制了通用程序,对合成甲醇体系上机进行计算,结果与文献值相符.
The characteristics of the restricted complex reaction system which are different from the general reaction equilibrium system are described. The introduction of additional material conservation restrictions and the calculation of the composition of the restricted complex reaction system by the free energy minimization method are introduced. A general procedure has been developed to calculate the synthesis methanol system. The results are in accordance with the literatures.