合成了高氯酸镝二苯亚砜Ｄｙ（ＤＰＳＯ）６（ＣｌＯ４）３、六氟磷酸镝二苯亚砜Ｄｙ（ＤＰＳＯ）７（ＰＦ６）３、高氯酸镝苯丁基亚砜Ｄｙ（ＰＢＳＯ）６（ＣｌＯ４）３三个配合物．测定了配合物的组成、摩尔电导及粉晶荧光激发和发射光谱，根据光谱实验结果计算了配体的Ｓ１及Ｄｙ３＋的第一激发态及基态能级．通过对三个配合物的荧光发射光谱的研究知：Ｄｙ（ＤＰＳＯ）６（ＣｌＯ４）３的发光强度最高，其中４Ｆ９２→６Ｈ１５２谱带强度高达１０６６ｃｄ．表明ＤＰＳＯ配体受激发后可将能量有效地传递给Ｄｙ３＋，另外在一定的条件下阴离ＣｌＯ－４可以增强Ｄｙ３＋的发光性能 Dysprosium phthalocyanine Dy (DPSO) 6 (ClO4) 3, Dysprosium hexafluorophosphate dipsylsulfone Dy (DPSO) 7 (PF6) 3, ) 6 (ClO4) 3 three complexes. The composition, molar conductance and fluorescence excitation and emission spectra of the complexes were determined. The first excited states and ground states of S1 and Dy3 + ligands were calculated according to the experimental results. The fluorescence emission spectra of the three complexes show that the luminescence intensity of Dy (DPSO) 6 (ClO4) 3 is the highest, and the intensity of 4F92 → 6H152 band is up to 1066cd. It is shown that the DPSO ligand can efficiently transfer energy to Dy3 + after being excited, and that ClO-4 can enhance the luminescent properties of Dy3 + under certain conditions