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合成了6种固态含能配合物M(BTA)(phen)m·nH2O(M=Mn,Co,Ni,Zn,m=2,n=5;M=Cu,m=2,n=1;M=Pb,m=1,n=1;BTA=N,N′-二四唑胺,phen=1,10-菲咯啉),并对它们进行了表征.用RD 496-CK2000型微热量计测定了298.15 K下各配合物的液相生成反应焓ΔrHmθ;改变反应温度,在实验和计算基础上,得到了液相生成反应的热力学参数(活化焓、活化熵和活化自由能),速率常数和动力学参数(表现活化能、频率因子和反应级数).
Six kinds of solid state energetic complex M (BTA) (phen) m · nH2O were synthesized with M = Mn, Co, Ni and Zn, m = 2 and n = M = Pb, m = 1, n = 1; BTA = N, N’-ditetrazolam and phen = 1,10-phenanthroline) The enthalpies of formation of liquid phase reaction, ΔrHmθ, were calculated at 298.15 K. The thermodynamic parameters (enthalpy of activation, activation entropy and activation free energy) of liquid phase reaction were obtained on the basis of experiment and calculation. The reaction rate Constants and kinetic parameters (expression of activation energy, frequency factor and reaction order).