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Rg2-N2O (Rg =Ne, Ar, and Kr) trimers are the typical system to study the non-additivity three-body effects.In this paper, rovibrational spectra of the van der Waals trimers Ne2-N2O and Ar2-N2O are studied in the ν1 region of N2O-monomer using an infiared tunable diode laser spectrometer to probe a pulsed supersonic jet.