Structural and electrical properties of Ti-W-N thin films deposited by reactive RF sputtering

来源 :第四届国际表面与界面科学与工程学术会议(The Fourth International Conference on S | 被引量 : 0次 | 上传用户:yukon_hawk
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  Ti-W-N thin films were deposited by reactive RF sputtering with a W-Ti(30 at.%) target in an argon/nitrogen atmosphere.The nitrogen partial pressure ratio in the growth chamber was varied from 0 to 11%.The influence of the nitrogen partial pressure ratio on the properties of Ti-W-N thin films was studied.The electrical resistivity of the Ti-W-N thin films varied gradually from 117.5 μΩ·cm to 675 μΩ·cm with the increase of nitrogen partial pressure ratio from 0 to 5.88%.However,the resistivity increased sharply if the ratio was raised further.X-ray photoelectron spectroscopy (XPS) analysis showed that nitrogen concentration in the films increased with the nitrogen partial pressure ratio and reached 36% when the ratio was 11%.Binding energy analysis showed that W was mainly in W2N and Ti was mainly in TiN when the film contained a nitrogen concentration of 36%.X-ray diffraction (XRD) analysis confirmed that an f.c.c mixed phase W2N/TiN was present in the film.Moreover,the temperature coefficient of resistance and the micromachining of the Ti-W-N thin films were investigated.All the results above show that the Ti-W-N thin films are good candidate materials for dynamic infrared scene generation application.
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