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China is abundant in coal resource and suffering from the heavy pollution caused by coal burning in the air.Supercritical water gasification is a clean and effective method in converting coal with no nitrogen oxide and sulfur oxideemission.Polycyclic aromatic hydrocarbons are found the component of the coal matrix and is referred to as the last hurdle of coal complete gasification.Anthracene is selected as the model compound of polycyclic aromatic hydrocarbons to explore the gasification mechanism of coal in autoclaves.