【摘 要】
：
铜(Ⅰ)配合物因其结构类型独特和光化学物理性质优良,在光电功能信息材料领域有着良好的应用前景[1,2]。本文选择应用功能化吡啶吡唑螯合配体和1,4-双(二苯膦)丁烷(dppb)
【机 构】
：
江西理工大学 冶金与化学工程学院,江西 赣州,341000
论文部分内容阅读
铜(Ⅰ)配合物因其结构类型独特和光化学物理性质优良,在光电功能信息材料领域有着良好的应用前景[1,2]。本文选择应用功能化吡啶吡唑螯合配体和1,4-双(二苯膦)丁烷(dppb)辅助配体,设计合成了一系列1,4-双(二苯膦)丁烷桥联的双核铜(I)配合物1-3,通过改变吡唑环上取代基的电子性质和空间位阻,实现了对光致发光性质的结构调控,应用TD-DFT 方法对发光性质进行了理论计算和分析研究。
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