TiO2-graphene (TOG) composites with exposed TiO2 {001} facets was prepared by solvothermal approach without any addition of surfactants or capping agents,only using titanium isopropoxide and graphene oxide ethanol suspenison as precursors.Graphene in TOG was covered by uniform and dense anatase TiO2 nanoparticles,exposing the {001} facets.