Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Buta-2,3-dien Amines

来源 :中国化学会第十六届全国有机合成化学学术研讨会 | 被引量 : 0次 | 上传用户：hhugjl012800

【摘要】

：

A mild and efficient reaction of [2,3]-sigmatropic rearrangement of quaternary buta-2,3-dien ammonium ylides via in situ activation of tertiary buta-2,3-dien amines with arynes has been developed.

【作者】

：

Lu Han Shi-Kai Tian

【机构】

：

Department of Chemistry,University of Science and Technology of China,Hefei,Anhui 230026,China

【出处】

：

中国化学会第十六届全国有机合成化学学术研讨会

【发表日期】

：

2019年3期

【关键词】

：

[2 3]-Sigmatropic Rearrangement Allenyl Amines Arynes Conjugated Dienes

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　　A mild and efficient reaction of [2,3]-sigmatropic rearrangement of quaternary buta-2,3-dien ammonium ylides via in situ activation of tertiary buta-2,3-dien amines with arynes has been developed.

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Aryne-Mediated [2,3]-Sigmatropic Rearrangement of Tertiary Buta-2,3-dien Amines

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