杂环配体修饰的{CuCN}配位聚合物的合成及荧光性质研究

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：dreamyear

【摘要】

：

含{CuCN}的聚合物具有新颖的结构,在气体吸附、催化剂、荧光材料和抗肿瘤等方面具有潜在的应用,但其合成的原料多为剧毒KCN,限制了其深入研究,探索使用低毒反应物合成其聚合物,是材料学者、化学工作者关注之一,因此,本文利用水热合成技术,选择低毒K4[Fe(CN)6]为反应物,通过调节反应物浓度、控制反应温度、反应时间、选择不同杂环有机配体等方法合成了九种以{CuCN}为基本骨架的金属有机配位聚合物

【作者】

：

徐慧苏占华于凯周百斌

【机构】

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哈尔滨师范大学化学化工学院,黑龙江哈尔滨,150025

【出处】

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第九届全国无机化学学术会议

【发表日期】

：

2015年7期

【关键词】

：

CuCN 水热合成配位聚合物荧光性质杂环配体

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杂环配体修饰的{CuCN}配位聚合物的合成及荧光性质研究

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