Monolayers of molecules can be formed at a variety of interfaces,and over the years many techniques have been developed to construct them and to study the resulting organisation of the molecules.At a liquid-solid interface,2D assemblies can be created by depositing a solution of the compound of interest on top of the substrate.Depending on the nature of the solvent,the substrate,and the dissolved molecules,the latter might form an ordered monolayer at the liquid-solid interface.When the interactions remain relatively weak,the process is called physisorption.Advanced interface specific methods such as scanning tunneling microscopy (STM) are needed to study the interface at the nanoscopic level.[1,2]