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In order to develop polymer materials as protective coatings,much attention has been focused on the fluorinated polymer,which is able to create a surface performing low surface free energy and thus high water-and oil-repellency.In this work,a set of different core-shell fluorosilicone acrylate copolymer(BA/MMA/DFHM and BA/MMA/DFHM/MPTMS/D4)latexes and linear pentablock fluorosilicone acrylate copolymer(PDMS-b-(PMMA-b-PDFHM)2)solutions have been synthesized.